Each homologous series has a class name that must be distinguished from the name of the functional group that it contains. This means that the compounds are identical with the exception of the number of ch2 units in the compound. There are primary, secondary and tertiary alcohols. The independent variables are the molar mass of the compound and the identity and position of the functional group a control variable is that i will only look at. Why is ethanol a member of the homologous series of alcohols but propane is not.
Alcohols alcohol homologous series, classifying alcohols, physical properties, reactions of alcohols. Inorganic compounds include the oxides of carbon, the bicarbonates and carbonates of metal ions, the metal cyanides, and a few others. The carboxylic acids may be attached to an alkyl radical to give an aliphatic acid, or attached directly to a benzene ring and give aromatic acid, the saturated monocarboxylic aliphatic acids are named fatty acids because many of them are present in fats in the form of an ester with glycerol, the carboxylic acids cooh is the functional group of organic acids, it is composed of two groups. Organic chemistry is the chemistry of carbon containing compounds the melting and boiling point increases as you increase carbons in a homologous series benzene is an.
Which formula represents the first member of the benzene series. Homologous series, alkanes, alkenes, alcohols, carboxylic acids, esters. They are organic because they contain hydrogen and carbon atoms. The defining characteristic of a homologous series is a repeating unit. Functional groups and homologous series, carboxylic acids. Alkanes have nonpolar bonds because the electro negativity of hydrogen and carbon atoms are similar. Homologous series have the same general formula with the neighbouring members of the series differing by ch 2. Alcohols alcohols gcse chemistry single science revision. Alcohol refers to any chemical having an oh functional group hydroxyl bound to a saturated carbon atom.
These atoms or groups attached are known as functional groups and the series formed are all homologous series. They all contain the functional group oh, which is responsible for the properties. At the same time, the solubility of this homologous series of alcohols increases in nonpolar solvents like hexane and benzene. In some cases, you can substitute one alcohol for another or use a mixture of alcohols. Successive members of a homologous series differ by a ch2 group. A homologation reaction, also known as homologization, is any chemical reaction that converts the reactant into the next member of the homologous series. A ethanol has two carbon atoms per molecule but propane has three. Ethanol and dimethyl ether have different chemical and physical properties because they have different athe number of covalent bonds per molecule is greater bthe molecules are more symmetrical. Alcohols are named from the corresponding molecule they derive from. Alcohol is an homologous series in which the compounds contain a functional group called the hydroxyl group oh. Those data are not readily available, but a quick experiment will verify it.
Alcohols with one to four carbon atoms are frequently called by common names, in which the name of the alkyl group is followed by the word alcohol. For example, the alkane group contains the ch2 repeating unit. Functional groups and homologous series, chloroalkanes question 4. Functional groups and homologous series carboxylic acids, rcooh. This means all alcohols have similar physical and chemical properties. They all contain the functional group oh, which is responsible for the properties of alcohols. Homologous series, any of numerous groups of chemical compounds in each of which the difference between successive members is a simple structural unit. A homologous series is a group of compounds that differ by a constant unit, generally a ch 2 group. Naming and drawing including shortened structural formula for straight chain alcohols. Hydroxyl carbonyl amino carboxyl 2 a homologous series of alcohols contains a different number of carbon atoms, but the same number of hydroxyl groups. The successive members vary from each other by a ch 2 unit. Why does solubility of homologous series decrease as.
The homologous series of alcohols all contain the oh grouping. For example in ch 4 and c 2 h 6, the difference is ch 2 unit and the difference between c 2 h 6 and c 3 h 8 is also ch 2 unit. Organic chemistry topic notes 7 alcohols a homologous series similar to alkanes but with a hydrogen replaced by an oh hydroxyl group. The series of carbon compounds in which two successive compounds differ by ch 2 unit is called homologous series. Changes in physical properties in homologous series. But but1ene would tell us that the double bond starts on the first carbon atom in the chain that is ch 3 ch 2 chch 2 above. The alcohols have higher boiling points than alkanes with the same number of carbon atoms. The increased amount of nonpolar interactions in the alcohols increases their affinity with nonpolar solvents. A hydrocarbon homologous series is a series of hydrocarbons which. Alcohol molecules all contain the hydroxyl oh functional group. Alcohols are hydrocarbon compounds containing one or more hydroxyl group o h attached to a saturated carbon atom. For many series of compounds, lengthening of a saturated carbon side chain from one methyl to five to nine atoms pentyl to nonyl produces an.
Carboxylic acids with two or more carboxyl groups attached are called dicarborxylic acids. In this lesson package, we will be studying in depth on alcohols, an homologous series containing the oh group, and carboxylic acids, as a homologous series containing the co 2 h group. B ethanol can be made from ethene but propane is obtained from petroleum. The solubility of a homologous series of organic compounds in water decreases with increasing chain length because water molecules become increasingly less able to participate in the strong dispersion interactions between the longchained organic. Alkenes contain double covalent bonds a bond that has two shared electrons. Alcohols alcohol homologous series naming alcohols. The alcohols are a homologous series of organic compounds.
A homologous series is a family of hydrocarbons with similar chemical properties who share the same general formula. Primary alcohols are when the carbon attached to the hydroxyl group touches one other. This makes them more reactive than corresponding alkanes. It contains about 5% of impurities, mainly carbon, sulfur, silicon and phosphorus, which have to be removed when this iron is converted into steel. The longest continuous chain lcc of carbon atoms containing the oh. They are saturated because they only contain single bonds so no additional atoms can be added to them. The homologous series of alcohols class contains the hydroxyl functional group. Alcohols nomenclature and classification chemistry.
D ethanol contains the same functional group as other alcohols but propane. Homologous series examples, answers, activities, experiment. The alcohols which only contain one hydroxyl group attached to a saturated carbon form a homologous series. Alcohols have a polar oh bond because of difference in electronegativity of o and h atoms. Oh, which is responsible for the properties of alcohols. Organic compounds also have functional groups, which define the basic properties of the compound. Homologous series of alkanes decane nonane octane hexane heptane butane pentane ch propane ch4 ethane 3 ch 3 ch3 ch 2 8 ch3 ch3 ch 2 7 ch3 ch3 ch 2 6 ch3 ch ch 2 4 ch ch3 ch 2 5 ch3. To which series does the hydrocarbon with the structure shown below belong. The reactants undergo a homologation when the number of a repeated structural unit in the molecules is increased. Homologous series of alkanes, alkenes and alkynes with. Pearson edexcel certificate pearson edexcel international. The first two members of the homologous series of alcohols are methanol and ethanol.
The corresponding homologous series of primary straightchained alcohols comprises methanol ch4o, ethanol c2h6o, 1propanol c3h8o, 1butanol, and. The first three alcohols in the homologous series are methanol, ethanol and propanol. Alcohols alcohols higher chemistry revision bbc bitesize. Principle cetyl alcohol is as palmitic acid ester the major component of spermaceti. There are a number of homologous series of hydrocarbon compounds which contain various functional groups that are derived from alkanes, alkenes, alkynes and benzene. The following table contains a listing of the names and structures of the first 10 members of the alkane family of hydrocarbons. Such series are most common among organic compounds, the structural difference being a methylene group, as in the paraffin hydrocarbons, or alkanes. However, each alcohol is a distinct molecule, with its own melting point, boiling point, reactivity, toxicity, and other properties.
Methanol ch 3 oh and ethanol ch 3 ch 2 oh are the first two members of the homologous series of alcohols. Since alkanes only contain single bonds between c atoms they are said to. There are four different homologous series of organic compounds discussed here. Which homologous series contains the compound toluene. A homologous series is a family of organic compounds. Functional groups and homologous series, alcohols question 5. We can make ethanol by fermenting glucose with yeast.
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